Methyl N′-[(E)-1-phenylethylidene]hydrazinecarboxylate
نویسنده
چکیده
The mol-ecule of the title compound, C(10)H(12)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the phenyl ring and the hydrazine carboxylic acid mean plane is 25.23 (9)°. In the crystal structure, mol-ecules are linked into chains by N-H⋯O hydrogen bonds and C-H⋯π inter-actions.
منابع مشابه
(E)-Methyl N′-[1-(4-methylphenyl)ethylidene]hydrazinecarboxylate
The title mol-ecule, C(11)H(14)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 7.61 (16)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O hydrogen bonds and the dimers are linked together by C-H⋯π inter-actions.
متن کامل(E)-Benzyl(1-phenylethylidene)amine
The title compound, C15H15N, represents an E isomer. The mol-ecule exhibits a minor [9.1 (2)%] disorder with methyl-benzyl-idene and benzyl groups inter-changing their positions. The C=N bond length is 1.292 (2) Å. The mol-ecular geometry is essentially planar, with the maximal twist of 8.5 (3)° for the benzyl group. The herringbone packing arrangement does not exhibit any π-stacking inter-acti...
متن کاملMethyl (E)-N′-[1-(2,4-dihydroxyphenyl)ethylidene]hydrazinecarboxylate
The mol-ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl-ate plane is 3.01 (6)°. An intra-molecular O-H⋯N hydrogen bond is observed. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (10) by O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds.
متن کامل(E)-Methyl N′-[1-(4-hydroxyphenyl)ethylidene]hydrazinecarboxylate
The title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazine carboxylic acid plane is 8.29 (7)°. Mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯O, O-H⋯N hydrogen bonds and C-H⋯π inter-actions.
متن کامل(E)-Methyl N′-(2-hydroxybenzylidene)hydrazinecarboxylate at 123 K
In the title mol-ecule, C(9)H(10)N(2)O(3), the hydrazinecarboxylic acid mean plane and the benzene ring form a dihedral angle of 11.1 (1)°. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains extending along the b axis. An intra-molecular O-H⋯N hydrogen bond is also present.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008